Publications & Patents

Publications

Minnick, D. L.; Gilbert, W. J. R.; Rocha, M. A.; Shiflett, M. B., “Thermodynamic Measurement and Modeling of Vinyl Fluoride Solubility in Aqueous Lithium Bis(trifluoromethylsulfonyl)imide Li+Tf2N- + H2O solutions.” Journal of Fluid Phase Equilibrium, In Press 2017.

Gilbert, W. J. R.; Minnick, D. L.; Rocha, M. A.; Shiflett, M. B., “Physical Properties of Water + Lithium bis(trifluromethylsulfonyl)imide Solutions.” Journal of Chemical Engineering Data, In Press 2017.

Cramer, H., Chirag, M., Salonga, S., Shockey, C., Chen, Ru., Colby, D., Dhurjati, P., Shiflett, M. Chemical Engineering Senior Laboratory The University Of Delaware, Journal of Chemical Engineering Education201650, 2, 131-140.

Mather, B.D., Reinartz, N.M., Shiflett, M.B., Polymerization of Vinyl Fluoride in Ionic Liquid and Ionic Solutions, Polymer201682, 295-304.

Gao, J., Ndong, R.S., Shiflett, M.B., Wagner, N.J. Creating Nanoparticle Stability in Ionic Liquid [C4mim][BF4] by Inducing Solvation Layering, ACSNano20159, 3243-3253.

Delluva, A., Salonga, S., Steward, B., Arivalagan, J., Lehr, R., Dhurjati, P., Shiflett, M. Chemical Engineering Junior Laboratory And The New Kinetics Experiment At The University Of Delaware, Journal of Chemical Engineering Education201549, 3, 149-156.

Shiflett, M.B., Corbin, D.R., Elliott, B.A., Subramoney, S., Kaneko, K., Yokozeki, A. Sorption of Trifluormethane in Activated Carbon, Adsorption201420, 565-575.

Shiflett, M.B., Corbin, D.R., Elliott, B.A., Yokozeki, A. Sorption of Trifluoromethane in Zeolites and Ionic Liquid, J. Chem. Thermo.201364, 40-49.

Shiflett, M.B., Yokozeki, A. “Solubility of Gases in Ionic Liquids”, in Ionic Liquids: UnCOILed, ACS Symposium Series, N.V. Plechkova, K.R. Seddon, Eds., Wiley 2013, pp. 349-386.

Shiflett, M.B., Corbin, D.R., Yokozeki, A. Comparison of the Sorption of Trifluoromethane (R-23) on Zeolites and in an Ionic Liquid, Ads. Sci. & Tech.201331, 59-83.

Shiflett, M.B., Elliott, B.A., Yokozeki, A. Chemical Absorption of Carbon Dioxide in Room-Temperature Ionic Liquid 1-ethyl-3-ethylimidazolium acetate [eeim][Ac], ChemPhysChem.201213, 1806-1817.

Shiflett, M.B., Niehaus, A.M.S., Cheney, B.A., Yokozeki, A. Phase Behavior of N2O and CO2 in Room-Temperature Ionic Liquids [bmim][Tf2N], [bmim][BF4], [bmim][N(CN)2], [bmim][Ac], [eam][NO3] and [bmim][SCN], Int. J. Thermophysics201233, 412-436.

Shiflett, M.B., Elliott, B.A., Yokozeki, A. Separation of N2O and CO2 using Room-Temperature Ionic Liquid [bmim][Ac], J. Sep. Sci. Tech.201247, 411-421.

Shiflett, M.B., Yokozeki, A. Phase Behavior of Vinyl Fluoride in Room-Temperature Ionic Liquids [emim][Tf2N], [bmim][N(CN)2], [bmpy][BF4], [bmim][HFPS] and [omim][TFES], Fluid Phase Equilibria.2011316, 147-155.

Shiflett, M.B., Yokozeki, A. Solubility of N2O and CO2 in Olive Oil, J. Fluid Phase Equilibria2011305, 127-131.

Shiflett, M.B., Shiflett, A.D, Yokozeki, A. Separation of Tetrafluoroethylene and Carbon Dioxide using Ionic Liquids, J. Sep. Pur. Tech., 201179, 357-364.

Shiflett, M.B., Niehaus, A.M.S., Yokozeki, A. Separation of N2O and CO2 using Room-Temperature Ionic Liquid [bmim][BF4], J. Phys. Chem. B , 2011115, 3478-3487.

Shiflett, M.B., Yokozeki, A. Water Solubility in Ionic Liquids and Application to Absorption Cycles, Ind. Eng. Chem. Res., 201049, 9496-9503.

Yokozeki, A., Shiflett, M.B. Gas Solubilities in Ionic Liquids using a Generic van der Waals Equation of State, J. Supercritical Fluids201055, 846-851.

Shiflett, M.B., Niehaus, A.M.S., Yokozeki, A. Separation of CO2 and H2S using Room-Temperature Ionic Liquid [bmim][MeSO4], J. Chem. Eng. Data201055, 4785-4793.

Shiflett, M.B., Drew, D.D., Cantini, R.A., Yokozeki, A. Carbon Dioxide Capture using Ionic Liquid 1-butyl-3-methylimidazolium acetate, Energy Fuels, 201024, 5781-5789.

Shiflett, M.B., Yokozeki, A. Separation of CO2 and H2S Using Room-Temperature Ionic Liquid [bmim][PF6], Fluid Phase Equilibria2010294, 105-113.

Shiflett, M.B., Yokozeki, A. Chemical Absorption of Sulfur Dioxide in Room-Temperature Ionic Liquids, Ind. Eng. Chem. Res., 201049, 1370-1377.

Shiflett, M.B., Yokozeki, A. Separation of Carbon Dioxide and Sulfur Dioxide Using Room-Temperature Ionic Liquid [bmim][MeSO4], Energy Fuels201024, 1001-1008.

Shiflett, M.B., Niehaus, A.M.S., Liquid-Liquid Equilibria in Binary Mixtures Containing Substituted Benzenes with Ionic Liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, J. Chem. Eng. Data20101, 346-353.

Ren, W., Scurto, A.M., Shiflett, M.B., Yokozeki, A. Phase Behavior and Equilibria of Ionic Liquids and Refrigerants: 1-ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide ([EMIm][Tf2N]) and R-134a, in Gas-Expanded Liquids and Near-Crticial Media: Green Chemistry and Engineering, ACS Symposium Series No. 1006, Hutchenson, K.W., Scurto, A.M., Subramaniam, B., Eds. Amercian Chemical Society: Washington, D.C. 2009 pp. 112-128.

Yokozeki, A., Shiflett, M.B. Separation of Carbon Dioxide and Sulfur Dioxide Gases Using Room-Temperature Ionic Liquid [hmim][Tf2N], Energy Fuels200923, 4701-4708.

Shiflett, M.B., Niehaus, A.M.S, Yokozeki, A. Liquid-Liquid Equilibria in Binary Mixtures Containing Chlorobenzene, Bromobenzene, and Iodobenzene with Ionic Liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, J. Chem. Eng. Data200954, 2090-2094.

Shiflett, M.B., Yokozeki, A. Solubility of Fluorocarbons in Room Temperature Ionic Liquids, in Ionic Liquids: From Knowledge to Application, ACS Symposium Series No. 1030, Plechkova, N.V., Rogers, R.D., Seddon, K.R., Eds. American Chemical Society: Washington, D.C. 2009 pp. 21-42.

Shiflett, M.B., Yokozeki, A. Phase behavior of carbon dioxide in ionic liquids: [emim][acetate], [emim][trifluoroacetate], and [emim][acetate] + [emim][trifluoroacetate] mixtures, J. Chem. Eng. Data200954, 108-114.

Yokozeki, A., Shiflett, M.B., Junk, C.P., Grieco, L.M., Foo, T. Physical and Chemical Absorptions of Carbon Dioxide in Room-Temperature Ionic Liquids, J. Phys. Chem. B2008112, 16654-16663.

Shiflett, M.B., Yokozeki A, Liquid-Liquid Equilibria in Binary Mixtures containing Fluorinated Benzenes and Ionic Liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, J. Chem. Eng. Data, 200853, 2683-2691.

Yokozeki, A., Shiflett, M.B., Binary and Ternary Phase Diagrams of Benzene, Hexafluorobenzene, and Ionic Liquid [emim][Tf2N] using Equations of State, Ind. Eng. Chem. Res., 200847, 8389-8395.

Shiflett, M.B., A. Yokozeki, Binary Vapor-Liquid and Vapor-Liquid-Liquid Equilibria of Hydrofluorocarbons (HFC-125 and HFC-143a) and Hydrofluoroethers (HFE-125 and HFE-143a) with Ionic Liquid [emim][Tf2N], J. Chem. Eng. Data200853, 492-497.

Kumelan, J., A.P.-S. Kamps, D. Tuma, A. Yokozeki, M.B. Shiflett, G. Maurer, Solubility of tetrafluoromethane in the ionic liquid [hmim][Tf2N], J. Phys. Chem. B2008112, 3040-3047.

Shiflett, M.B., A. Yokozeki, Phase Equilibria of Hydrofluorocarbon-4310mee Mixtures with Ionic Liquids:  Miscibility of Threo– and Erythro– Diastereomers in Ionic Liquids, Ind. Eng. Chem. Res., 200847, 926-934.

Shiflett, M.B., D.J. Kasprzak, C.P. Junk, A. Yokozeki, Phase Behavior of Carbon Dioxide + [bmim][Ac] Mixtures, J. Chem. Thermodynamics200840, 25-31.

Shiflett, M.B., A. Yokozeki, Liquid-Liquid Equilibria of Hydrofluoroethers and Ionic Liquid [emim][Tf2N], J. Chem. Eng. Data200752, 2413-2418.

Shiflett, M.B., A. Yokozeki, Solubility Differences of Halocarbon Isomers in Ionic Liquid [emim][Tf2N], J. Chem. Eng. Data200752, 2007-2015.

Shiflett, M.B., A. Yokozeki, Hydrogen Substitution Effect on the Solubility of Perhalogenated Compounds in Ionic Liquid [bmim][PF6], Fluid Phase Equilibrium2007259, 210-217.

Yokozeki, A., D.J. Kasprzak, M.B. Shiflett, Thermal Effect on C-H Stretching Vibrations of the Imidazolium Ring in Ionic Liquids, Phys. Chem. Chem. Phys., 20079, 5018-5026.

Shiflett, M.B., A. Yokozeki, Liquid Liquid Equilibria in binary Mixtures of 1,3-Propanediol + Ionic Liquids [bmim][PF6], [bmim][BF4], and [emim][BF4], J. Chem. Eng. Data200752, 1302-1306.

Yokozeki, A., D.J. Kasprzak, M.B. Shiflett, IR-Spectroscopy Studies of Hydrogen-Bonding Solutions:  Lineshape Analysis of Ethanol + Hexane System, Applied Energy200784, 863-873.

Yokozeki, A., M.B. Shiflett, Vapor-Liquid Equilibria of Ammonia + Ionic Liquid Mixtures, Applied Energy200784, 1258-1273.

Shiflett, M.B., A. Yokozeki, Solubility of CO2 in Room-Temperature Ionic Liquid [hmim][Tf2N], J. Phys. Chem. B, 2007111, 2070-2074.

Yokozeki, A., M. B. Shiflett, Ammonia Solubilities in Room-Temperature Ionic Liquids, Ind. Eng. Chem. Res., 200746, 1605-1610.

Yokozeki, A., M.B. Shiflett, Hydrogen Purification Using Room-Temperature Ionic Liquids, Applied Energy200784, 351-361.

Shiflett, M.B., A. Yokozeki, Vapor-Liquid-Liquid Equilbiria of Hydrofluorocarbons and 1-Butyl-3-Methylimidazolium Hexafluorophosphate, J. Chem. Eng. Data200651, 1931-1939.

Shiflett, M.B., A. Yokozeki, Vapor-Liquid-Liquid Equilbiria of Pentafluoroethane and Ionic Liquid [bmim][PF6] Mixtures Studied with the Volumetric Method, J. Phys. Chem. B2006110, 14436-14443.

Yokozeki, A., M.B. Shiflett, Global Phase Behaviors of Trifluoromethane in Room-Temperature Ionic Liquid [bmim][PF6], AIChE Journal200652, 3952-3957.

Shiflett, M.B., A. Yokozeki, Separation of Difluoromethane and Pentafluoroethane by Extractive Distillation using Ionic Liquid, Chemistry Today200624, 28-30.

Shiflett, M.B., A. Yokozeki, Gaseous Absorption of Fluoromethane, Fluoroethane, and 1,1,2,2-Tetrafluoroethane in 1-Butyl-3-Methylimidazolium Hexafluorophosphate, Ind. Eng. Chem. Res., 200645, 6375-6382.

Shiflett, M.B., M.A. Harmer, C.P. Junk, A. Yokozeki, Solubility and Diffusivity of 1,1,1,2-tetrafluoroethane in Room-Temperature Ionic Liquids, Fluid Phase Equilibr., 2006242, 220-232.

Shiflett, M.B., M.A. Harmer, C.P. Junk, A. Yokozeki, Solubility and Diffusivity of Difluoromethane in Room-Temperature Ionic Liquids, J. Chem. Eng. Data200651, 483-495.

Shiflett, M.B., A. Yokozeki, Solubility and Diffusivity of Hydrofluorocarbons in Ionic Liquids, AIChE J., 200652, 1205-1219.

Shiflett, M.B., A. Yokozeki, Solubilities and Diffusivities of Carbon Dioxide in Ionic Liquids: [bmim][PF6] and [bmim][BF4].  Ind. Eng. Chem. Res., 200544, 4453-4464.

Shiflett, M.B., H.C. Foley, Reproducible Production of Nanoporous Carbon Membranes. Carbon200139, 1421-1446.

Shiflett, M.B., H.C. Foley, A. Yokozeki,  Theoretical Calculation of Polymer Deposition Thickness on a Cylindrical Substrate.  AIChE J., 200147, 1648-1663.

Shiflett, M.B., H.C. Foley, On the Preparation of Supported Nanoporous Carbon Membranes.  J. Membr. Sci., 2000179, 275-282.

Shiflett, M.B., J.F. Pedrick, S.R. McLean, S. Subramoney, H.C. Foley, Characterization of Supported Nanoporous Carbon Membranes.  Adv. Mater., 200012, 21-25.

Shiflett, M.B., H.C. Foley, Ultrasonic Deposition of High-Selectivity Nanoporous Carbon Membranes.  Science1999285, 1902-1905.

Shiflett, M.B., S.I. Sandler, Modeling Fluorocarbon Vapor-Liquid Equilibria using the Wong-Sandler Model.  Fluid Phase Equilibria1998147, 145-162.

Shiflett, M.B., D.B. Bivens, A. Yokozeki, R-22 Alternatives for Air Conditioners and Heat Pumps.  ASHRAE Transactions technical symposium paper SD-95-12, 1995101, 557-565.

Shiflett, M.B., D.B. Bivens, A. Yokozeki, HCFC-22 Alternatives for Air Conditioners and Heat Pumps.  ASHRAE Transactions technical symposium paper OR-94-01, 1994100, 566-572.

Shiflett, M.B., A. Yokozeki, Performance Evaluation of R-502 and R-22 Alternatives in a Compressor Calorimeter.  Proceedings of the 1994 International Compressor Engineering Conference at Purdue, West Lafayette, Indiana:  Purdue University19941, 401-406.

Shiflett, M.B., A. Yokozeki, K.N. Mumpower, Calorimeter Experiments with an HCFC-22 Alternative in a Reciprocating Compressor.  Proceedings of the 1994 International Compressor Engineering Conference at Purdue, West Lafayette, Indiana:  Purdue University19941, 61-66.

Shiflett, M.B., HCFC-22 Alternatives for Air Conditioners and Heat Pumps.  Proceedings of the 1994 International Compressor Engineering Conference at Purdue, West Lafayette, Indiana:  Purdue University19941, 1-6.

Shiflett, M.B., A. Yokozeki, Near Azeotropic Refrigerants as Alternatives for R-502.  ASHRAE Journal199335, 24-28.

Shiflett, M.B., A. Yokozeki, P.R. Reed, Property and Performance Evaluation of SUVA® HP Refrigerants as R-502 Alternatives. Proceedings of the 1992 International Compressor Engineering Conference at Purdue, West Lafayette, Indiana:  Purdue University19921, 15-24.

Shiflett, M.B., A. Yokozeki, D.B. Bivens, Refrigerant Mixtures as HCFC-22 Alternatives. Proceedings of the 1992 International Compressor Engineering Conference at Purdue, West Lafayette, Indiana:  Purdue University19921, 35-44.

Shiflett, M.B., Alternative Low Temperature Refrigerants.  Proceedings of the XVIII International Congress of Refrigeration1991163, 122.


Patents

Shiflett, M.B., Mikeska, K.R.  Bioderived Biodegradable Lubricant 2015: US Patent 13/712,496.

Shiflett, M.B., Elliott, B.A. Process For The Production Of Carbon Fibers From Poly(α(1-→3) Glucan) Fibers 2015:  US Patent 9,096,956.

Shiflett, M.B. Capture of Trifluoromethane using Ionic Liquids 2015:  US Patent 2015/0082981 A1

Shiflett, M.B., Corbin, D.R. Capture of Trifluoromethane using Molecular Sieves 2015:  US Patent 2015/0087869A1

Shiflett, M.B., Yokozeki, A. Foamed Ionic Compounds 2015:  US Patent 8,946,442.

Shiflett, M.B., Yokozeki, A. Process and Reactor System for producing Ammonia using Ionic Liquids 2014:  US Patent 8,808,659.

Shiflett, M.B., Noelke, C.J. Capture of Fluorinated Vinyl Monomers using Ionic Liquids 2014:  US Patent 8,779,220.

Shiflett, M.B., Yokozeki, A. Process for purifying perfluorinated products. 2014:  US Patent 8,771,626.

Shiflett, M.B., Foo, T., Harmer, M.A., Hutchenson, K.W., Junk, C.P., Mellein, B.R., Minter, A., Carbon Dioxide Removal and Ionic Liquid Compounds Useful Therein. 2014:  US Patent 8,721,770.

Shiflett, M.B., Yokozeki, A. Absorption Cycle Utilizing Ionic Liquid as Working Fluid. 2014:  US Patent 8,715,521.

Shiflett, M.B., Yokozeki, A. Hybrid Vapor Compression-Absorption Cycle. 2014:  US Patent 8,707,720.

Shiflett, M.B., Yokozeki, A. Utilizing Ionic Liquids for Hydrofluorocarbon Separation. 2014:  US Patent 8,628,644.

Shiflett, M.B., Yokozeki, A. Vapor Compression Cycle utilizing Ionic Liquids as Compressor Lubricants. 2013:  US Patent 8,568,608.

Shiflett, M.B., Yokozeki, A. Absorption cycle utilizing Ionic Liquids and Water as Working Fluids. 2013:  US Patent 8,506,839.

Shiflett, M.B., Subramaniam, S., Lustig, S.R., Gai, P.L. Storage Materials for Hydrogen and other small molecules. 2013:  US Patent 8,454,921.

Shiflett, M.B., Yokozeki, A. Process for Separation of Tetrafluoroethylene from Carbon Dioxide using Ionic Liquids. 2012:  US Patent 8,313,558.

Shiflett, M.B., Corbin, D.R., Griffin, T.P., Hutchenson, K.W., Li, S., Torardi, C., Zaher, J.J. Processes for Producing Titanium Dioxide. 2012:  US Patent 8,137,647.

Shiflett, M.B., Yokozeki, A. Process for the Separation of Diastereomers. 2011: US Patent 8,075,777.

Shiflett, M.B., Yokozeki, A., Knapp, J.P. Process for the Separation of Fluorocarbons Using Ionic Liquids. 2011:  US Patent 7,964,760.

Shiflett, M.B., Yokozeki, A. Hybrid Vapor Compression-Absorption Cycle. 2010:  US Patent 7,765,823.

Shiflett, M.B., Subramaniam, S., Lustig, S.R., Gai, P.L. Storage Materials for Hydrogen and other small molecules. 2010:  US Patent 7,731,931.

Shiflett, M.B., Corbin, D.R. and Foley, H.C. Mixed Matrix Nanoporous Carbon Membranes. 2004:  US Patent 6,740,143.

Shiflett, M.B., Bivens, D.B., and Yokozeki, A. Near-Azeotropic Blends for use as Refrigerants. 1998:  US Patent 5,800,730.

Shiflett, M.B. Substantially Constant Boiling Compositions of Difluoromethane and Trifluoroethane. 1998:  US Patent 5,788,877.

Shiflett, M.B., Yokozeki, A., and Minor, B.H. Refrigeration Process using azeotropic compositions of perfluoroethane and trifluoromethane. 1998:  US Patent 5,766,503.

Shiflett, M.B. Air Conditioner and Heat Pump with Tetrafluoroethane-containing Working Fluid. 1998: US Patent 5,722,256.

Shiflett, M.B. Refrigeration Process using Constant Boiling Compositions of HFC-32, HFC-125, and HFC-134a. 1998:  US Patent 5,709,092.

Shiflett, M.B., Yokozeki, A.  Azeotropic or Azeotrope-Like Compositions of Ammonia and Tetrafluoroethane.  1997: US Patent 5,700,388.

Shiflett, M.B., Bivens, D.B., Chisolm-Carter, T. Use of 1,1,1,3,3,3-Hexafluoropropane in Centrifugal Compressors. 1997:  US Patent 5,662,825.

Shiflett, M.B. Constant Boiling Compositions of HFC-32, HFC-125, and HFC-134a. 1997:  US Patent 5,643,492.

Shiflett, M.B., Bivens, D.B., Yokozeki, A. Near-azeotropic Blends for use as Refrigerants with pentafluoroethane, trifluoromethane, and tetrafluoroethane. 1997:  US Patent 5,635,099.

Shiflett, M.B., Bivens, D.B., Yokozeki, A. Azeotrope-Like Refrigerants with Chlorodifluoromethane, Pentafluoroethane, and C2-C4 Hydrocarbon. 1997:  US Patent 5,616,276.

Shiflett, M.B., Bivens, D.B. Compositions of Difluoromethane and Tetrafluoroethane. 1996:  US Patent 5,589,098.

Shiflett, M.B., Klug, D.L., Yokozeki, A., Chisolm, T.C. Compositions of 2,2-dichloro-1,1,1-tri-fluoroethane and pentafluoropropane. 1995:  US Patent 5,447,646.

Shiflett, M.B., Bivens, D.B., Yokozeki, A. Constant Boiling Compositions of Fluorinated Hydrocarbons. 1995:  US Patent 5,403,504.

Shiflett, M.B. Yokozeki, A. Azeotropic or Azeotrope-like Compositions of Ammonia and Hydrocarbons.  1995: US Patent 5,387,357.

Shiflett, M.B., Van Bramer, D., Yokozeki, A. Safe Handling of Tetrafluoroethylene. 1994:  US Patent 5,345,013.

Shiflett, M.B., Bivens, D.B. Compositions of Difluoromethane and Tetrafluoroethane. 1994:  US Patent 5,290,466.

Shiflett, M.B., Bivens, D.B., and Yokozeki, A. Near-Azeotropic Blends for use as Refrigerants. 1994:  US Patent 5,277,834.

Shiflett, M.B., Felix, V.M. Binary Azeotropic Mixtures of Octafluoropropane and Fluoroethane. 1993:  US Patent 5,248,433.

Shiflett, M.B. Mixtures of Perfluoropropane and Trifluoroethane. 1993:  US Patent 5,236,611.

Shiflett, M.B. Substantially Constant Boiling Compositions of Difluoromethane and Propane. 1993:  US Patent 5,234,613.

Shiflett, M.B. Substantially Constant Boiling Compositions of Difluoromethane and Trifluoroethane or Perfluoroethane. 1993:  US Patent 5,232,618.

Shiflett, M.B. Constant Boiling Compositions of Pentafluoroethane, Difluoromethane, and Tetrafluoroethane.  1993: US Patent  5,185,094.